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6PPD-L CAS 793-24-8

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Chemical Name : N- (1,3- Dimethylbutyl)- N’- phenyl- p- phenylenediamine

CAS NO. :  793-24-8

Product Specification:

AppearanceGrey Purple to Purplish Brown Pastilles or flakes
Purity(GC),%97.0
Melting Point(Initial),°C45.0
Freezing Point,°C46.0
Heat Loss(70±2℃ ),%0.30
Ash,%0.10

  Performance:
-Modified from 6PPD, 6PPD-L has significantly less odor and VOC and is much less volatile compared with 6PPD. It can effectively reduce the odor of rubber compound and final products.
-6PPD-L has the same performance with 6PPD in other aspects.

  Application:

-6PPD-L and 6PPD have the same performance and can be applied interchangeably.

-It is recommended that 6PPD-L be applied to rubber products with higher requirements for odor and VOC, such as tires, conveyor belts, and rubber hoses.

  Packaging: Paper/plastic packages with a net weight of 25kg per package.

  Transportation Condition: Clear vehicle with ceiling, avoiding sunshine,  rain and long-term extrusion,keeping away from hot source.

793-24-8 – Names and Identifiers

NameN-1,3-dimethylbutyl-N’-phenyl-p-phenylenediamine
SynonymsBHTOX-4020
Flexzone 7F
Vulkanox 4020
Santoflex6PPD
Antoxidant 6ppd
Antoxidant 4020
Santoflex 134PD
Antioxidant 4020
N-(1,3-Dimethylbutyl
Rubber Antioxidant 4020
SANTOFLEX(R) 13 PASTILLES
Rubber Antioxidant 4020PPD
N-1,3-dimethylbutyl-N’-phenyl-p-phenylenediamine
N-(1,3-Dimethylbutyl)-N-Phenyl-1,4-Benzenediamine
N-(1,3-Dimethylbutyl)-N-Phenyl-p-phenylene Diamine
N-(1,3-Dimethylbutyl)-N’-phenyl-p-phenylenediamine
N-(1.3-dimethylbutyl)-N’-phenyl-p-phenylenediamine
N-(4-methylpentan-2-yl)-N’-phenylbenzene-1,4-diamine
1,4-BenzenediaMine,N1-(1,3-diMethylbutyl)-N4-phenyl-
N1-(4-methylpentan-2-yl)-N4-phenyl-benzene-1,4-diamine
1-N-(4-methylpentan-2-yl)-4-N-phenylbenzene-1,4-diamine
4020,N-(1,3-DiMethylbutyl)-N’-phenyl-p-phenylenediaMine
CAS793-24-8
EINECS212-344-0
InChIInChI=1/C18H24N2/c1-14(2)13-15(3)19-17-9-11-18(12-10-17)20-16-7-5-4-6-8-16/h4-12,14-15,19-20H,13H2,1-3H3
InChIKeyZZMVLMVFYMGSMY-UHFFFAOYSA-N

793-24-8 – Physico-chemical Properties

Molecular FormulaC18H24N2
Molar Mass268.4
Density0.986~1.00g/cm3
Melting Point45-46°C
Boling Point260°C
Flash Point204°C
Water Solubility<0.1 g/100 mL at 17 ºC
Solubilitysoluble in Methanol
Vapor Presure5.22E-07mmHg at 25°C
AppearanceDark brown black solid
ColorLight orange to Dark red to Black
pKa6.73±0.32(Predicted)
Storage ConditionKeep in dark place,Sealed in dry,Room Temperature
Refractive Index1.6300 (estimate)
MDLMFCD00072248
Physical and Chemical PropertiesGray-black solid.
UseNatural rubber and synthetic rubber with anti-ozone agent and antioxidant, ozone crack and flex fatigue excellent protective effect

793-24-8 – Risk and Safety

Risk CodesR22 – Harmful if swallowed
R43 – May cause sensitization by skin contact
R50/53 – Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety DescriptionS36/37 – Wear suitable protective clothing and gloves.
S60 – This material and its container must be disposed of as hazardous waste.
S61 – Avoid release to the environment. Refer to special instructions / safety data sheets.
UN IDsUN 3077 9 / PGIII
WGK Germany2
RTECSST0900000
HS Code29215190
Hazard Class9
Packing GroupIII
ToxicityLD50 oral in rat: 3580mg/kg

793-24-8 – Reference Information

purposethe product is a polluting antioxidant, in addition to good Antioxidant efficacy, and anti-ozone, anti-bending to find the role of cracking and inhibition of copper, manganese and other harmful metals. Its performance is similar to that of antioxidant 4010NA, but its toxicity and skin irritation are smaller than 4010NA, and its solubility in water is better than 4010NA (water loss rate: 4010NA is 50%, and 4020 only 15-20%). Can be widely used in the preparation of tires, tape and many other industrial rubber products, the general dosage of 0.5-1.5%. This product is not suitable for making light-colored products due to serious pollution. Antioxidant 4020 is one of the main varieties of p-phenylenediamine antioxidant. P-phenylenediamine antioxidant is the main good varieties commonly used in rubber industry at home and abroad, and it is also the development direction of antioxidant in the future.
It is an antiozonant and antioxidant for natural rubber and synthetic rubber, and has excellent protective effect against ozone cracking and flex fatigue
production methoda variety of methods can be used to prepare antioxidant 4020. Generally, 4-aminodiphenylamine is obtained by catalytic hydrocondensation with methyl isobutyl ketone. N-(1, 3-dimethylbutyl)-p-aminophenol can also be used to react with aniline at 210-230 °c under the catalysis of iron powder and iodine (or FeCI2, FeCI3), after the condensation reaction is completed, the mixture of the product is obtained by distilling off the volatile substances at 180 ° C. (133 Pa), which is divided into: N-(1, 3-dimethylbutyl)-N’-phenyl-p-phenylenediamine 50%,N,N’-diphenyl-p-phenylenediamine 17.5%,N,N’-bis (1, 3-dimethylbutyl)-p-phenylenediamine 13.4%.

Declaration: The products displayed on this website are intended exclusively for industrial applications or scientific research. They are not intended for medical, pharmaceutical, or food use. In accordance with applicable laws and regulations, purchasing organizations must hold valid qualifications and approvals.

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