Dimethyl Carbonate (CAS No. 616-38-6)
1. Basic Information
Chemical Name: Dimethyl Carbonate
Synonyms: DMC; Methyl carbonate; Carbonic acid dimethyl ester
CAS Number: 616-38-6
Molecular Formula: C₃H₆O₃
Molecular Weight: 90.08 g/mol
Appearance: Colorless liquid
Odor: Mild, ester-like odor
2. Physical and Chemical Properties
Melting Point: 2–4 °C (36–39 °F)
Boiling Point: 90 °C (194 °F)
Density: 1.07 g/cm³ (at 20 °C)
Solubility:Water: Slightly soluble (13 g/L at 20 °C)Organic solvents: Miscible with alcohols, ethers, benzene
Refractive Index: 1.368–1.369 (20 °C)
Flash Point: 17 °C (63 °F) (closed cup) –
Highly FlammableVapor Pressure: 62 mmHg at 20 °C
3. Chemical Structure
O ║ CH₃-O-C-O-CH₃
4. Hazards (GHS Classification)
Flammability: Highly flammable liquid (H225)
Health Hazards:
Eye/Irritation: Causes mild irritation (H319)
Inhalation: May cause dizziness or respiratory tract irritation (H336)
Environmental Hazards: Low toxicity to aquatic life (H402)
NFPA Rating: Health 1, Flammability 3, Reactivity 0
5. Storage and Handling
Storage: Store in a cool, well-ventilated area away from heat/sparks/open flames. Use explosion-proof equipment.
Handling: Use PPE (gloves, goggles, vapor respirator) and ground containers to prevent static discharge.
6. Applications
Green Solvent: Replacement for toxic solvents (e.g., MTBE, DCM) in coatings, adhesives.
Chemical Synthesis: Methylating/ carbonylating agent in pharmaceuticals (e.g., pesticides, polycarbonates).
Electrolytes: Used in lithium-ion batteries.
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