Sodium Carboxymethyl Cellulose (CAS No. 9004-32-4)
1. Basic Information
Chemical Name: Sodium carboxymethyl cellulose
Synonyms: CMC; Cellulose gum; Carmellose sodium
CAS Number: 9004-32-4
Molecular Formula: [C₆H₇O₂(OH)ₓ(OCH₂COONa)ᵧ]ₙ
Molecular Weight: Variable (typically 90,000–700,000 g/mol)
Appearance: White to cream-colored powder
Odor: Odorless
Substitution Degree (DS): 0.6–1.0 (commercial grades)
2. Physical and Chemical Properties
Melting Point: Decomposes before melting (~260°C/500°F)
Density: 0.5–0.7 g/cm³ (bulk density)
Solubility:Water: Forms viscous colloidal solutionOrganic solvents: Insoluble in ethanol, acetone, ether
pH (1% solution): 6.5–8.5
Viscosity (1% solution): 5–10,000 mPa·s (depends on grade)
Moisture Content: ≤10% (as supplied)
3. Hazards (GHS Classification)
Acute Toxicity: Not classified (Hazard statements generally not required)
Skin/Eye Irritation: May cause mild irritation (H315/H319)
Inhalation Risk: Dust may cause respiratory irritation (H335)
Environmental Impact: Not hazardous (H420 not applicable)
NFPA Rating: Health 1, Flammability 1, Reactivity 0
4. Storage and Handling
Storage:Keep in tightly sealed containersStore in cool (<30°C), dry conditionsProtect from moisture caking
Handling:Use dust mask (NIOSH N95) when handling powderSafety goggles recommended for bulk handling
5. Applications
Food Industry: Thickener (E466), stabilizer in ice cream/sauces
Pharmaceuticals: Tablet binder, viscosity modifier in syrups
Personal Care: Toothpaste thickener, shampoo viscosity agent
Industrial: Paper coating, textile sizing, oil drilling fluid additive
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